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The main psychoactive component in liberty caps, psilocybin, works on the portion of the brain that helps regulate both arousal and panic responses to different stimuli. Unlike LSD, liberty caps do not always cause significant visual hallucinations. It differs by affecting and distorting how people that are on the drug perceive the reality around them. They often experience relatively large degrees of distorted perception for several hours after ingestion.
Once ingested liberty caps can take effect and enter the system in about 30 minutes. After this, the effects will increase to a plateau, where they will remain for approximately 4-6 hours following the dosing. In rare cases this change in perception can actually last for days after consumption, often leading to a significant effect on the life of the user.